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Step-wise laser excitation of the 4snf 3F Rydberg states of neutral zinc
Authors:Mehmood Shah  Ghulam Aisha  Shaista Shahzada  Sami-ul-Haq
Institution:1. National Institute of Lasers and Optronics (NILOP), Islamabad, Pakistan;2. Department of Physics, International Islamic University, Islamabad, Pakistan
Abstract:The new experimental results on the effective quantum numbers and term energies of the highly excited odd-parity 4s4d 3D1,2,3 →4snf 3F2,3,4 Rydberg transitions of zinc have been presented. The experiment was performed using the three dye lasers simultaneously pumped by the second harmonic (532?nm) of the Q-switched Nd:YAG laser. The new observation includes the 4snf 3F3 (12?≤n?≤?50) series excited from the 4s4d 3D2 intermediate level. In addition, the 4snf 3F2 (12?≤n?≤?28) and 4snf3F4 (12?≤n?≤?33) series are observed from the thermally populated 4s4d 3D1,3 fine structure components. The ionization potential of zinc has been determined from the unperturbed 4snf 3F3 series as 75769.31?±?0.15?cm?1, which is in excellent agreement with the previously reported value.
Keywords:Ionization potential  odd-parity states  Rydberg states  zinc
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