Rhodium macrocyclic complexes: The synthesis and single crystal X-ray structure of [Rh([18]aneN2S4)](PF6)3 · 3H2O ([18]aneN2S4 = 1,4,10,13-tetrathia-7,16-diazacyclooctadecane) |
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Authors: | Alexander J Blake Gillian Reid Martin Schrder |
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Institution: | Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, Scotland, U.K. |
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Abstract: | Reaction ofRh(H2O)6]3+ with one molar equivalent of 18]aneN2S4 in refluxing MeOH-H2O (1 : 1 v/v) for 12 h affords an orange solution from which the complex Rh(18]aneN2S4)](PF6)3 can be isolated upon addition of NH4PF6. A single crystal X-ray structure determination shows a distorted octahedral geometry at rhodium(III) involving the four thioether and two aza-donors of the macrocycle. The complex cation adopts a rac-configuration via meridional coordination of the two SCH2CH2NCH2CH2S linkages. |
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