High resolution spectroscopy using photodeflection

Isotope separation by laser deflection of an atomic beam, combined with simultaneous mass spectroscopy, has been used to determine optical frequency shifts and to assign mass numbers to all components of the $\text{Ba 6s}{}^2{}^1\text{S}{}_0\text{?6s6p}{}^1\text{P}{}_1$ 5536 Å resonance. Several components which cannot be resolved optically without the use of enriched samples, were resolved with the technique described. They are ${}^{135}\text{Ba}\text{(F=}\text{5}\text{2}\text{)}$ at 120 MHz, ¹³⁶Ba at 128 MHz and ¹³⁴Ba at 138 MHz.