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Spectre raman en phase vapeur du borazene: détermination des constantes de coriolis des espéces E |
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| Authors: | B. Roussel A. Chapput G. Fleury |
| Affiliation: | Université des Sciences et Techniques de Lille, U.E.R. de Chimie, Centre National de la Recherche Scientifique, Service de Spectrochimie Infrarouge, et Raman, Section de Lille C.5, B.P. 26, 59650, Villeneuve d''Ascq France;Centre I.N.S.E.R.M. de Technologie Biomédicale, Laboratoire de Physique, U.E.R. de Pharmacie, Rue du Professeur Laguesse, 59000, LilleFrance |
| Abstract: | The gas phase Raman spectrum of borazene has been recorded at medium resolution. The band contours of the E degenerate species have been observed and computer simulation of them has allowed the determination of the ζi values. This analysis has given the value of ζ19 and ζ20; ξ18 has been calculated from the “Zeta sum rules”. The gas phase spectrum of borazene is reported for the first time and assigned. |
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