Radiation emission coefficients for sulfur hexafluoride arc plasmas

Calculations are made of the total spectral absorptivities of plasmas of sulfur hexafluoride for wavelengths of 100 to 15,500 Å. Both line and continuum radiation are considered. For the contributions from line radiation, we have calculated the strengths, widths and shifts of both neutral, singly and doubly ionized atoms of S and F, except that we used experimental line strengths where they are available. The theory used was that of Griem, which assumes LS coupling. Curves are given for the emission coefficient of radiation appropriate to the arc center for isothermal cylindrical plasmas of various radii for pressures of 1 and 10 atm and temperatures from 5000 to 35,000°K. It is found that at 1 atm line radiation can be an order of magnitude higher than continuum radiation and radiation >2000 Å is less than 10% of the total radiation for temperatures greater than 15,000°K. Predictions are given of volt-ampere characteristics and central temperatures for arcs of various radii in SF₆ at pressures at 1 and 10 atm.