Enamine carboxylates as stereodetermining intermediates in prolinate catalysis |
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| Authors: | Hein Jason E Burés Jordi Lam Yu-hong Hughes Matthew Houk K N Armstrong Alan Blackmond Donna G |
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| Affiliation: | Department of Chemistry, The Scripps Research Institute, La Jolla, California 92037, USA. |
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| Abstract: | ![]()
Experimental and computational studies probing the nature of intermediates in the α-amination of aldehydes catalyzed by prolinate salts support an enamine carboxylate intermediate in the stereodetermining step. |
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