|
|||||
|
|
Synthesis of 1,4-diaryl-2-naphthoates based on site-selective Suzuki-Miyaura reactions |
|
| Authors: | Obaid-ur-Rahman Abid Muhammad Farooq Ibad Asad Ali Nasim Hasan Rama Peter Langer |
| Affiliation: | a Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany b Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan c Department of Chemistry, Allama Iqbal Open University, Islamabad, Pakistan d Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany |
| Abstract: | The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflates) of phenyl 1,4-dihydroxy-2-naphthoate afforded various 1,4-diaryl-2-naphthoates. The reactions proceeded with very good site-selectivity. Due to electronic reasons, the first attack occurred at the sterically more hindered position C-1. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |