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Remarkable enhancement effect of potassium tert-butoxide/THF solution in base-induced Sommelet-Hauser rearrangements |
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| Authors: | Eiji Tayama Keisuke Takedachi Hajime Iwamoto Eietsu Hasegawa |
| Institution: | Department of Chemistry, Faculty of Science, Niigata University, Niigata 950-2181, Japan |
| Abstract: | A solution of potassium tert-butoxide in THF was shown to remarkably enhance the base-induced Sommelet-Hauser rearrangement of N-benzylic amino acid-derived ammonium ylides. |
| Keywords: | Rearrangement Pericyclic reaction Ammonium salt Ylide Amino acid |
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