The first ‘alkane-like’ functionalization of n-alkyl acetates: a new method for one-pot selective syntheses of bifunctional aliphatic compounds with an acetate group |
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| Authors: | Alexander V Orlinkov |
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| Institution: | A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, 119991, Moscow, GSP-1, 28 Vavilova Street, Russia |
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| Abstract: | Selective one-pot functionalization of linear alkyl acetates CnH2n + 1OCOMe (n = 6, 8), with CO and various nucleophilic substrates (iso-propanol, morpholine, piperidine, and anisole) in the presence of the superelectrophilic system CBr4·2AlBr3 is performed for the first time. |
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| Keywords: | n-Alkyl acetates Functionalization Superelectrophiles Functionalized alkyl acetates |
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