Novel generation of an o-quinone methide from 2-(2'-cyclohexenyl)phenol by excited state intramolecular proton transfer and subsequent C-C fragmentation |
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Authors: | Delgado Julio Espinós Amparo Jiménez M Consuelo Miranda Miguel A |
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Affiliation: | Departamento de Química-Instituto de Technología Química UPV-CSIC, Camino de vera s/n, 46071 Valencia, Spain. |
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Abstract: | Formation of an o-quinone methide via C-C fragmentation of a zwitterion formed by intramolecular excited state proton transfer from an o-allylphenol derivative is reported for the first time. |
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