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Speeds of sound,densities, isentropic compressibilities of the system (methanol + polyethylene glycol dimethyl ether 250) at temperatures from 293.15 to 333.15 K
Affiliation:1. School of Naval Architecture, Ocean and Civil Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;2. Department of Civil Engineering, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218, USA;1. Nanotechnology Research Center, School of Pharmacy, Mashhad University of Medical Sciences, Mashhad, Iran;2. Department of Immunology, Medical School, Shahid Beheshti University of Medical Sciences, Tehran, Iran;3. Center for Research and Training in Skin Diseases and Leprosy, Tehran University of Medical Sciences, Tehran, Iran;4. Biotechnology Department, Pasteur Institute of Iran, Tehran, Iran;5. Biotechnology Research Center, Nanotechnology Research Center, School of Pharmacy, Mashhad University of Medical Sciences, Mashhad, Iran;1. Department of Process & Analytical Chemistry, Merck Research Laboratories, Rahway, NJ, United States;2. Department of Chemistry, University of Heidelberg, Heidelberg, Germany
Abstract:
In this work, our objective is to contribute to the knowledge of the mixtures (alcohol + polyalkyl ether glycol) used in absorption refrigeration systems and heat pumps. The determination of different thermophysical properties is essential to understand the interactions among different molecules in liquid mixtures. Therefore, experimental data of speed of sound and density together with calculated values of isentropic compressibility for the refrigerant-absorbent system (methanol + polyethylene glycol dimethyl ether 250) (or Pegdme 250) have been gathered here over the whole range of composition at temperatures from T=293.15 to 333.15 K and atmospheric pressure. The two previous experimental properties were measured with a digital vibrating tube analyser Anton Paar DSA-48. Also, the excess molar volumes and the increments of the speed of sound and the isentropic compressibility have been determined for each composition and they were fitted to a variable-degree polynomial equation.
Keywords:
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