Electrical Properties of Molybdates in the Systems M2MoO4-AMoO4-Zr(MoO4)2 |
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Authors: | Bazarov B. G. Fedorov K. N. Bazarova S. T. Bazarova Zh. G. |
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Affiliation: | (1) Siberian Division, Russian Academy of Sciences, Baikal Institute of Nature Management, Ulan-Ude, Buryatiya, Russia;(2) Buryat State University, Ulan-Ude, Buryatiya, Russia |
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Abstract: | The temperature dependence of conductivity of molybdates in the systems M2MoO4-AMoO4-Zr(MoO4)2 was studied. The starting molybdates and molybdates of 5 : 1 : 3 and 1 : 1 : 1 compositions, formed in the systems, exhibit mixed conduction, turning ionic at high temperatures. The sharp bends in linear portions of the temperature dependence of conductivity coincide with the temperatures of polymorphic transitions in the corresponding molybdates. |
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