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Beiträge zur Chemie der Pyrrolpigmente, 9. Mitt.: Bildung,Struktur und Konfiguration vonZ- undE-Arylmethyliden-3,4-dimethyl-3-pyrrolin-2-onen
Authors:Doz. Dr. H. Falk  K. Grubmayr  O. Hofer
Affiliation:1. Lehrkanzel für Organische Chemie der Universit?t Wien, W?hringer Stra?e 38, A-1090, Wien, ?sterreich
Abstract:
The condensation of 3.4-dimethyl-3-pyrrolin-2-one with p-methyl-, p-chloro-benzaldehyde and ferrocenealdehyde yields theZ-andE-isomers of the corresponding condensates. Due to kinetic control theZ-isomers are obtained almost exclusively in this reaction. TheE-isomers of the two firstmentioned products can be produced by photochemical isomerization. The structures (tautomeric forms) and configurations of the isomers were established by the Lanthanide-induced-shift-technique and by evaluating the Nuclear-Overhauser-Effect.
Keywords:
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