Heavy atom effect on photophysical deactivation of molecular triplet states |
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| Authors: | E. A. Gastilovich S. A. Serov N. V. Korol’kova V. G. Klimenko |
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| Affiliation: | (1) State Scientific Center of the Russian Federation, Karpov Institute of Physical Chemistry, Moscow, 103064, Russia |
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| Abstract: | The decrease in the spin-orbit (SO) interaction with increasing number of chlorine atoms in molecules of dibenzo-p-dioxine derivatives is found and explained. The heavy atom effect on components of the rate constant of phosphorescence k ph=k SO+k VSO related to SO and vibronic-spin-orbit (VSO) interactions is quantitatively estimated. |
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