Stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin |
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| Authors: | Lira Ricardo Roush William R |
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| Affiliation: | Departments of Chemistry and Biochemistry, Scripps Florida, Jupiter, Florida 33458, USA. |
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| Abstract: | ![]()
[reaction: see text] A stereoselective synthesis of the C(1)-C(19) fragment of tetrafibricin has been accomplished via a highly diastereoselective double allylboration reaction of 6-8 and an iodonium ion promoted urethane cyclization for the installation of the C(15) alkoxy function in 3. |
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