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Copper-catalyzed dimerization fragmentation cyclization reactions of (E)-1-en-4-yn-3-ols as a versatile approach for the synthesis of multisubstituted 1H-cyclopenta[b]naphthalenes
Authors:Wang Xiang-Chuan  Hu Jie  Sun Peng-Shuai  Zhong Mei-Jin  Ali Shaukat  Liang Yong-Min
Affiliation:State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P. R. China.
Abstract:
An intermolecular condensation reaction of 1,3,5-triarylenynols catalyzed by copper is developed. This reaction is a straightforward method for the synthesis of highly conjugated 1H-cyclopenta[b]naphthalene. Fluorescent properties have been determined for some of the products.
Keywords:
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