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Determination of thorium concentrations in soil and sand samples using instrumental neutron activation analysis
Authors:D G Mishra  R Acharya  K K Swain  R M Joshi  V M Joshi  P C Verma  A G Hegde  A V R Reddy
Institution:1. Health Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India
2. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India
3. Analytical Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India
Abstract:Thorium along with its daughter products present in the soil is one of the major contributors to the external gamma dose in the environment. To establish the dose levels, quantification of thorium contents in soil samples is very important. As a part of pre-operational environmental radiological surveillance, a total of 23 soil and six sand samples were collected from different locations around the proposed nuclear power plant site of Jaitapur, Maharashtra. Thorium concentrations in these samples were determined by instrumental neutron activation analysis (INAA). Samples were irradiated with neutrons in Apsara reactor at a neutron flux of?~5?×?1011 cm?2 s?1 and radioactive assay was carried out using high resolution gamma ray spectrometry. Relative method of INAA was used for quantification of thorium utilizing 311.9?keV gamma ray of 233Pa, the daughter product of 233Th. The concentrations of thorium in the soil and sand samples were in the ranges of 4.0?C18.8 and 1.2?C6.2?mg?kg?1 respectively.
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