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| 无机锡催化δ-酮腈异构化成吡啶酮反应的研究 | |
| 引用本文： | 张振权,高世萍,孙强,孙云鸿,毛丽娟. 无机锡催化δ-酮腈异构化成吡啶酮反应的研究[J]. 有机化学, 1993, 13(6): 623-626 |
| 作者姓名： | 张振权 高世萍 孙强 孙云鸿 毛丽娟 |
| 作者单位： | 东北师范大学化学系，东北师范大学化学系，东北师范大学化学系，东北师范大学化学系，东北师范大学化学系 吉林，长春，130024，吉林，长春，130024，吉林，长春，130024，吉林，长春，130024，吉林，长春，130024 |
| 摘 要： | 本文分别对三种无机锡(SnCl~2,SnO和SnO~2)催化δ-酮腈异构化成吡啶酮的条件进行了考察。实验结果表明:SnCl~2和SnO具有很高的催化活性。 |
| 关 键 词： | 催化 锡 吡啶酮 异构化 腈 乙基化 酮 |
The study on isomerization of δ-keto nitriles to pyridones catalyzed by inorganic tin |
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| ZHANG Zhen-Quan,GAO Shi-Ping,SUN Qiang,SUN Yun-Hong,MAO Li-Juan. The study on isomerization of δ-keto nitriles to pyridones catalyzed by inorganic tin[J]. Chinese Journal of Organic Chemistry, 1993, 13(6): 623-626 | |
| Authors: | ZHANG Zhen-Quan GAO Shi-Ping SUN Qiang SUN Yun-Hong MAO Li-Juan |
| Affiliation: | NE Normal Univ, Dept Chem.Changchun(130024) |
| Abstract: | It is reported that the isomerization of δ-keto nitriles was catalyzed by inorganic tin to give 5, 6-dialkyl-3, 4-dihydro-2- pyridones. The results showed that both SnCl~2 and SnO had high catalytic activity for this isomerization. |
| Keywords: | catalyzed by inorganic tin isomerization cyanoethylation |
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