The pyrolysis of trimethylgermane and trimethylsilane期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The pyrolysis of trimethylgermane and trimethylsilane

Authors:	D. P. Paquin R. J. O'Connor M. A. Ring

Affiliation:	Department of Chemistry, San Diego State University, San Diego, California 92115 U.S.A.

Abstract:	The number of products and the H₂/CH₄ ratio obtained from the flow pyrolyses of (CH₃)₃GeH and (CH₃)₃SiH were very different. The (CH₃)₃GeH decomposition is consistent with the following mechanism: Full-size image The pyrolysis of (CH₃)₃SiH was found to be much more complex, presumably due to the formation of silicon-carbon double bonded intermediates and the (CH₃)₂Si(H)CH₂ radical. We also present data which supports the presence of a H atom chain sequence during this pyrolysis.

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