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Expedient synthesis of villosin and its isomer (E)-labda-8(17),12,14-trien-15(16)-olide |
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| Authors: | John Boukouvalas Jian-Xin Wang Olivier Marion |
| Institution: | Département de Chimie, Université Laval, Quebec City, Que., Canada G1K 7P4 |
| Abstract: | The synthesis of the title compounds has been achieved in concise, highly regiocontrolled fashion from commercially available (+)-sclareolide. In addition, we offer evidence that the structure of a newly reported natural product from Zingiber ottensii is incorrect. |
| Keywords: | Aldol reaction 2-Furanolates Labdanes Lactones Misassigned structure Villosin |
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