| [Ni(en)3]4[HVⅣ12VⅤ6O42(PO4)]复合物的合成及晶体结构 |
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| 引用本文： | 郑寿添,曾庆新,林之恩,杨国昱.[Ni(en)3]4[HVⅣ12VⅤ6O42(PO4)]复合物的合成及晶体结构[J].无机化学学报,2002,18(12):1233-1236. |
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| 作者姓名： | 郑寿添 曾庆新 林之恩 杨国昱 |
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| 作者单位： | 中科院福建物质结构研究所,结构化学国家重点实验室,福州,350002 |
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| 基金项目： | 国家自然科学基金资助项目(No.20171045)、国家财政部和中科院"引进国外杰出人才"专项基金资助项目及福建省自然科学基金资助项目(No.E0210029). |
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| 摘 要： | A new complex Ni(en)3]4HVⅣ12VⅤ6O42(PO4)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system,space group Im 3m with a=17.4081(2)?, V=5275.38(10)?3, R=0.0420, wR=0.1055, Z=2, Dc=1.663g·cm-3, μ=2.297mm-1, F(000)=2636. The crystal structure consists of Ni(en)3]2+ cations and {HV18O42(PO4)}8- cluster anion which construct from 18 {VO5} square pyramids. The VO5 pyramids joined each other to form a {V18O42} cage hosting a tetrahedral {PO4}3- moiety with disordered oxygen atoms. CCDC: 185574.
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| 关 键 词： | 水热合成 多氧钒酸盐 晶体结构 |
| 修稿时间： | 2002年5月10日 |
Synthesis and Crystal Structure of Complex [Ni(en)3]4[HVⅣ12VⅤ6O42(PO4)] |
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| ZHENG Shou-Tian,ZENG Qing-Xin,LIN Zhi-En and YANG Guo-Yu.Synthesis and Crystal Structure of Complex [Ni(en)3]4[HVⅣ12VⅤ6O42(PO4)][J].Chinese Journal of Inorganic Chemistry,2002,18(12):1233-1236. |
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| Authors: | ZHENG Shou-Tian ZENG Qing-Xin LIN Zhi-En and YANG Guo-Yu |
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| Institution: | Coordination and Hydrothermal Chemistry Group, State Key Laboratory of the Structural Chemistry, Fujian Institurte of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,Coordination and Hydrothermal Chemistry Group, State Key Laboratory of the Structural Chemistry, Fujian Institurte of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,Coordination and Hydrothermal Chemistry Group, State Key Laboratory of the Structural Chemistry, Fujian Institurte of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 and Coordination and Hydrothermal Chemistry Group, State Key Laboratory of the Structural Chemistry, Fujian Institurte of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 |
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| Abstract: | |
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| Keywords: | hydrothermal synthesis polyoxovanadate crystal structure |
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