Sonochemical syntheses of a straw-like nano-structure two-dimensional mixed-ligand zinc(II) coordination polymer as precursor for preparation of nano-sized ZnO |
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Authors: | Mojtaba Khanpour Ali Morsali Pascal Retailleau |
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Institution: | 1. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran;2. Service de Cristallochimie, Institut de Chimie des Substances Naturelles-CNRS, Bât 27, 1 Avenue de la Terrasse, 91190 Gif sur Yvette, France |
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Abstract: | Straw-like nano-structure of a new mixed-ligand Zn(II) two-dimensional coordination polymer, {Zn(μ-4,4′-bipy)(μ-3-bpdb)(H2O)2](ClO4)2·4,4′-bipy·3-bpdb·H2O}n (1) {4,4′-bipy = 4,4′-bipyridine and 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene}, was synthesized by a sonochemical method. The new nano-structure was characterised by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compound 1 was structurally characterised by single crystal X-ray diffraction and consists of two-dimensional polymeric units. ZnO nanoparticles were obtained by calcination of compound 1 at 500 °C under air atmosphere and were characterised by X-ray diffraction (XRD) and scanning electron microscopy (SEM). |
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Keywords: | Nano-structure 4 4&prime -Bipyridine 1 4-Bis(3-pyridyl)-2 3-diaza-1 3-butadiene Coordination polymer Zinc(II) Zinc(II) oxide |
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