Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes |
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| Authors: | PE Kleyi CW McClelandTIA Gerber |
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| Institution: | Department of Chemistry, Nelson Mandela Metropolitan University, P.O. Box 77000, Port Elizabeth 6031, South Africa |
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| Abstract: | The solvent-free reaction of ferrocenecarboxaldehyde and diaminoalkanes under solvent-free conditions gave bisferrocenylimines (L) in excellent yields. Cationic rhodium(I) complexes with the formulation Rh(COD)(L)]ClO4 were prepared by the reaction of Rh(COD)Cl]2 with the bisferrocenylimines in the presence of silver perchlorate. The compounds were characterised by NMR, IR, MS and elemental analysis. The X-ray crystal structures of two rhodium(I) complexes are also reported. |
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| Keywords: | Solvent-free Bisferrocenylimines Rhodium(I) |
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