Co(II), Cu(II) and Zn(II) dinuclear complexes of a polypodal ligand containing phenolate and pyridyl donor groups |
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| Authors: | Jesú s Martí nez-Sá nchez,Rufina Bastida,Alejandro Mací as,Harry Adams,David E. Fenton,Paulo Pé rez-Lourido,Laura Valencia |
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| Affiliation: | 1. Departamento de Química Inorgánica, Universidad de Santiago de Compostela, Avda. de las Ciencias s/n 15782, Santiago de Compostela (La Coruña), Spain;2. Department of Chemistry, University of Sheffield, Dainton Building, Brook Hill, Sheffield S3 7HF, UK;3. Departamento de Química Inorgánica, Facultad de Química, Universidade de Vigo, 36310 Vigo (Pontevedra), Spain |
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| Abstract: | ![]()
Acetate and perchlorate dinuclear metal complexes of Co(II), Cu(II) and Zn(II) with the cresolate polypodal ligand having mixed phenolate and pyridyl pendant functionalities, H3L, have been synthesized. The complexes were characterized by microanalysis, LSI mass spectrometry, IR, UV–Vis spectroscopy, magnetic studies and conductivity measurements. Crystal structures of H3L, [Cu2(HL)(OAc)(H2O)2](OAc)·1.5H2O and [Zn2L(CH3OH)3](ClO4)CH3OH·2H2O complexes, have been also determined. |
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| Keywords: | Metal complexes Polypodal ligand Cresolate-bridge X-ray structure |
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