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Synthesis and Characterization of Mesoporous Titanosilicate as an Adsorbent for Toxic Metal Ions
Authors:Ahmadi Syed Javad  Sepehrian Hamid  Waqifhusain Syed  Faghihian Hossein  Alighanbari Hadi
Institution:1. NFCRS, Nuclear Science and Technology Research Institute, AEOI, P.O. Box 11365/8486, Tehran, Iran;2. Department of Chemistry, Faculty of Science, Science and Research Branch, Islamic Azad University, Tehran, Iran;3. Department of Chemistry, Faculty of Science, University of Isfahan, Isfahan, Iran;4. Faculty of Nuclear Engineering, University of Shahid Beheshti, Tehran, Iran
Abstract:Hexagonal mesoporous titanosilicates (Ti‐MCM‐41) have been prepared using cetyltrimethylammonium bromide (CTAB) as the structure directing agent under the mild alkaline conditions. Powder X‐ray diffraction, nitrogen gas sorption, FTIR spectroscopy and thermogravimetry analysis of samples have confirmed that well ordered MCM‐41 type mesoporous materials were prepared. The potential of removing toxic metal ions from waste waters using mesoporous titanosilicates was evaluated. Separation of CoII‐UVI, CsI‐UVI and SmIII‐UVI has been developed on columns of this adsorbent.
Keywords:mesoporous materials  titanosilicate  toxic metal ion  adsorption studies
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