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Electron transfer initiated Diels-Alder reaction with allenes as dienophiles |
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| Authors: | Michael Schmittel Clemens W hrle |
| Affiliation: | Institut für Organische Chemie und Biochemie der Universität Freiburg, Albertstr. 21, D-79104 Freiburg, Germany. |
| Abstract: | The first examples of using aryl allenes as dienophiles in the electron transfer induced Diels-Alder reaction are described. According to mechanistic tests the reaction proceeds via a cycloaddition of the diene+· to the allene. |
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