Rhodium(I) Tristyrylphosphine Cyclooctadiene Complexes |
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| Authors: | Nindakova L. O. Shainyan B. A. Albanov A. I. Malysheva S. F. Sukhov B. G. Trofimov B. A. |
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| Affiliation: | (1) Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia |
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| Abstract: | Rhodium complexes with unsaturated phosphines as ligands were studied by NMR spectroscopy. Tris[(E,Z,Z)-styryl)phosphine is a stronger complex-forming agent compared with tris[(Z,Z,Z)-styryl)phosphine in view of the easier accessibility of its lone electron pair. The composition of the complexes and their NMR parameters suggest a square-planar structure with cis phosphine ligands. |
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