| 基于分子催化剂光驱动水氧化器件的研究进展 |
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| 引用本文： | 高岩,段丽娜,张敏,孙立成.基于分子催化剂光驱动水氧化器件的研究进展[J].中国科学:化学,2014(4):625-630. |
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| 作者姓名： | 高岩 段丽娜 张敏 孙立成 |
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| 作者单位： | 大连理工大学精细化工国家重点实验室；大连理工大学人工光合作用研究所；大连理工大学一瑞典皇家工学院KTH分子器件联合研究中心,大连116024 |
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| 基金项目： | 国家自然科学基金(20923006,21003017,21120102036,21106015和91233201)的资助 |
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| 摘 要： | 光解水制氢是人们解决未来能源危机的一种重要构想,构建高效的光电化学池是实现这一构想的重要途径,而光驱动水氧化的顺利进行是实现这一过程的关键.本文总结了近年来基于分子催化剂及染料敏化的光驱动水氧化分子器件的研究和进展,介绍了这些分子器件的组装和性能研究等,并根据这些研究的优点和不足提出一些浅见.
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| 关 键 词： | 光解水 光电化学池 水氧化 分子器件 |
Research progress on molecular devices for light driven water oxidation |
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| GAO Yan＊,DUAN LiNa,ZHANG Min,SUN LiCheng.Research progress on molecular devices for light driven water oxidation[J].Scientia Sinica Chimica,2014(4):625-630. |
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| Authors: | GAO Yan＊ DUAN LiNa ZHANG Min SUN LiCheng |
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| Institution: | ＊ State Key Laboratory of Fine Chemicals; Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Center on Molecular Devices; Dalian University of Technology, Dalian 116024, China |
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| Abstract: | Utilizing solar energy to produce hydrogen from water is a great concept to resolve the energy crisis in future, and building up highly efficient photoelectrochemical cells is considered the important way to achieve this process. While in this process, the key challenge is to realize the light driven water oxidation smoothly. The developments of water oxidation molecular devices in recent years are summarized, the assembly and properties of these molecular devices are introduced in this paper, and some opinions are put forward according to these studies. |
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| Keywords: | light driven water splitting photoelectrochemical cells water oxidation molecular device |
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