| SYNTHESIS, SPECTRA AND ELECTROCHEMICAL PROPERTIES OF OXYGEN ADDUCTS OF TETRAKIS(2-ANILINOPYRIDINATO) DIRHODIUM COMPLEXES |
| |
| 作者姓名： | 刘鲁美 胡渝 龚四林 |
| |
| 作者单位： | Department of Chemistry，Beijing Normal University，Beijing 100875，PRC，Department of Chemistry，Beijing Normal University，Beijing 100875，PRC，Department of Chemistry，Beijing Normal University，Beijing 100875，PRC |
| |
| 摘 要： | Two oxygen adducts of different geometric isomers of the tetrakis(μ-2-anilinopyridinato) dirhodium unit, Rh_2(ap)_4~+, have been synthesized and characterized. Rh_2(ap)_4O_2(4,0) is the oxygen adduct 1 of 4, 0 isomer; and Rh_2(ap)_4O_2(2, 2) is the oxygen adduct 2 of 2, 2 isomer. The ESR spectra of both oxygen adducts show that there is a characteristic signal of a superoxide ion, g=2.03. The 4, 0 isomer with different axial ligands gives the order of A_Ⅱ values; O_2~-≈ClO_4~-
|
SYNTHESIS, SPECTRA AND ELECTROCHEMICAL PROPERTIES OF OXYGEN ADDUCTS OF TETRAKIS(2-ANILINOPYRIDINATO) DIRHODIUM COMPLEXES |
| |
| LIU LU-MEI HU YU GONG SI-LIN.SYNTHESIS, SPECTRA AND ELECTROCHEMICAL PROPERTIES OF OXYGEN ADDUCTS OF TETRAKIS(2-ANILINOPYRIDINATO) DIRHODIUM COMPLEXES[J].Science in China(Chemistry),1990(8). |
| |
| Authors: | LIU LU-MEI HU YU GONG SI-LIN |
| |
| Abstract: | |
| |
| Keywords: | oxygen adduct anilinopyridinato dirhodium complex spectra electrochemistry |
| 本文献已被 CNKI 等数据库收录！ |
