Molecular and crystal structures of (6R, 7R, 14S)-6,14-etheno-7-[(1R)-1-hydroxyethyl]- and (6R, 7R, 14S)-6,14-etheno-7-[(1S)-1-hydroxyethyl]-6,7,8,14-tetrahydro-17-nor-17-phenylthebaine |
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Authors: | I V Bakhanova V N Nesterov S K Moiseev H Schmidhammer V N Kalinin |
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Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) Institute of Pharmaceutical Chemistry, University of Innsbruck, 52a Innrain, A-6020 Innsbruck, Austria |
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Abstract: | The crystal structures and absolute configurations of (6R,7R,14S)-6,14-etheno-7-(1R)-1-hydroxyethyl]-6,7,8,14-tetrahydro-17-nor-17-phenylthebaine and (6R,7R,14S)-6,14-etheno-7-(1S)-1-hydroxyethyl]-6,7,8,14-tetrahydro-17-nor-17-phenylthebaine were established by X-ray diffraction analysis.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2245–2250, November, 1998. |
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Keywords: | morphine alkaloids thebaine X-ray diffraction analysis absolute configuration |
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