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Cleavage by halogens of carbon—cobalt bonds in organometallic complexes of cobalt(III) : III. Kinetics and mechanism of the reactions of organobis(dimethylglyoximato)cobalt(III) complexes with iodine in chloroform |
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| Authors: | RDreos Garlatti G Tauzher G Costa |
| Institution: | Institute of Chemistry, University of Trieste, 34127 Trieste Italy |
| Abstract: | The kinetics of the reaction between organocobaloximes, RCo(DH)2H2O, and iodine have been investigated. They reveal the participation of an RCo(DH)2H2O · I2 intermediate which undergoes intramolecular transalkylation and acts as an electrophile towards a second organocobaloxime molecule. The trend in reactivity as the R group is varied is discussed. |
| Keywords: | Author to whom correspondence should be addressed at his present address: Department of Chemistry University of Victoria Victoria B C V8W 2Y2 (Canada) |
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