首页 | 本学科首页   官方微博 | 高级检索  
     


Stereochimie de la reaction de rupture par le brome de la liaision siliciumaryle du dimethyl-1,2 phenyl-1 silacyclopentane
Authors:Jacques Dubac  Pierre Mazerolles  Monique Joly
Affiliation:Laboratoire des Organométalliques, Université P. Sabatier, 118 route de Narbonne, 31077-Toulouse-Cedex France
Abstract:
Stereospecific synthesis of geometric isomers of 1,2-dimethyl-1-phenylsilacyclopentane is described. We demonstrate that brominolysis of the arylsilicon bond occurs with predominant inversion of configuration at the silicon atom of the silacyclopentane ring.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号