Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides |
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Authors: | Larry I Shoer Kerrie I Gell Jeffrey Schwartz |
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Institution: | Department of Chemistry, Princeton University, Princeton, New Jersey 08540 U.S.A. |
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Abstract: | Dialkylaluminum hydrides and Cp2ZrX2 (Cp = π5-C5H5; X = Cl, H, alkyl) were found to react by aggregation to give mixed ZrAl trihydride complexes containing ZrHAl bridges. Reactions of these mixed-metal hydrides are discussed and structural parallels between them and known aluminum hydride complexes are drawn. |
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Keywords: | Author to whom correspondence should be addressed |
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