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The different steric environments of the 5-exo- and 5-endo- substituent for a pair of isomeric tricarbonyl(methoxycyclohexa-1,-diene)irons
Authors:Aubrey L Burrows  Brian FG Johnson  Jack Lewis  David G Parker
Institution:University Chemical Laboratory, Lensfield Road, Cambridge CB 1EW Great Britain
Abstract:A shift reagent has been employed to demonstrate the sterically-hindered environment of the methoxy group in tricarbonyl(5-endo-methoxycyclohexa-1,-diene)iron relative to that of the methoxy group in the 5-exo analogue.
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