α-Diimines as monodentate or bridging ligands; synthesis and characterization of palladium(II) and rhodium(I) di(t-butyl)diimine complexes |
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| Authors: | Henk Van Der Poel Gerard Van Koten Kees Vrieze |
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| Affiliation: | Anorganisch Chemisch Laboratorium, van ''t Hoff Instituut, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam The Netherlands |
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| Abstract: | ![]()
Complexes of di(t-butyl)diimine with PdCl2(PhCN)2 and with (CO)2RhCl dimer have been synthesized and characterized. The diimine ligand is monodentate bonded in PdCl2(t-butyldiimine)2, while in (t-butyldiimine)-[Rh(CO)2Cl]2 it bridges two Cl(CO)2Rh units. |
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