Solvent induced ionisation of η-allydicarbonylmolybdenum(II) complexes |
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| Authors: | BJ Brisdon M Cartwright |
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| Institution: | School of Chemistry, University of Bath, Bath BA2 7AY Great Britain |
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| Abstract: | MoCl(η-C3H5)(CO)2(MeCN)2] dissolved in aprotic solvents is extensively ionised to Mo(η-C3H5)(CO)2(MeCN)3]+Mo2Cl3(η-C3H5)2(CO)4]- with the liberation of free acetonitrile. The corresponding bromo- complex shows similar but less pronounced ionisation in (CD3)2CO, whereas the iodo-complex retains its molecular structure. |
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| Keywords: | Address any correspondence to this author |
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