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Gd3+→Tb3+的双光子敏化发光现象
引用本文:陈晓波 陈金铠. Gd3+→Tb3+的双光子敏化发光现象[J]. 发光学报, 1993, 14(2): 139-144
作者姓名:陈晓波 陈金铠
作者单位:1. 南开大学物理系, 天津 300071;2. 福建师范大学实验中心, 福州 350007
摘    要:本文首次报导了Tb0.7Gd0.3P5O14非晶在DCM染料激光的激发下,Gd3+→Tb3+的双光子敏化发光现象.在考虑了Judd-Pooler的自旋轨道相互作用三级微扰项之后,较好地解释了实验结果与Axe的二级双光子吸收理论的偏差.

关 键 词:稀土五磷酸盐非晶玻璃  Gd3+→Tb3+敏化发光  双光子吸收
收稿时间:1992-03-22

SENSITIZED LUMINESCENCE OF Tb~(3+) ION BY TWO-PHOTON ABSORPTION OF Gd~(3+) ION
Chen Xiaobo Chen Jinkai Zhang Guangyin Tian Jianguo Zhang Wanlin. SENSITIZED LUMINESCENCE OF Tb~(3+) ION BY TWO-PHOTON ABSORPTION OF Gd~(3+) ION[J]. Chinese Journal of Luminescence, 1993, 14(2): 139-144
Authors:Chen Xiaobo Chen Jinkai Zhang Guangyin Tian Jianguo Zhang Wanlin
Affiliation:1. Department of Physics, Nankai University, Tianjin 300071;2. Experiment Center, Fujian Normal University, Fuzhou 350007
Abstract:This paper reports the first observation of sensitized luminescence phenomenon of Tb3+ ion by two-photon absorption of Gd3 + ion in Tb0.7Gd0.3 p5O14 noncrystalline induced by pulsed DCM dye laser. In terms of two-photon absorption, there is a rather large deviation from the prediction of second order theory for 6P7/2,6P5/2 energy of Gd3+ ion. And it is necessary to take into account the contribution of third order spin-orbit interaction.
Keywords:rare earth penta-phosphate noncrystal glass  sensitized luminescence of Tb3+ ion by Gd3+ ion  two-photon absorption
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