Oxidative dearomatization of phenols and anilines via lambda(3)- and lambda(5)-iodane-mediated phenylation and oxygenation |
| |
| Authors: | Quideau Stéphane Pouységu Laurent Ozanne Aurélie Gagnepain Julien |
| |
| Institution: | Institut Européen de Chimie et Biologie and Laboratoire de Chimie des Substances Végétales, Centre de Recherche en Chimie Moléculaire, Université Bordeaux 1, France. s.quideau@iecb.u-bordeaux.fr |
| |
| Abstract: | Treatment of 2-methylphenols with chloro(diphenyl)-lambda(3)-iodane led to their regioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via a proposed ligand coupling reaction. In the same vein of investigation, treatment of 2-methylanilines with the lambda(5)-iodane 2-iodoxybenzoic acid IBX reagent led to their regioselective dearomatization into previously undescribed ortho-quinol imines. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
