| 单电子转移活性自由基聚合的现状及展望 |
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| 引用本文： | 丁伟,孙颖,吕崇福,魏继军,于涛. 单电子转移活性自由基聚合的现状及展望[J]. 应用化学, 2011, 28(3): 245-253. DOI: 10.3724/SP.J.1095.2011.00268 |
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| 作者姓名： | 丁伟 孙颖 吕崇福 魏继军 于涛 |
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| 作者单位： | (东北石油大学化学化工学院 大庆 163318) |
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| 基金项目： | 黑龙江省自然科学基金重点项目(ZJG0507);黑龙江省自然科学基金青年基金(QC08C33); 黑龙江省研究生创新科研资金(YJSCX2008-044HLJ); 黑龙江省科技厅攻关项目(GZ05A404)资助 |
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| 摘 要： | 重点介绍了单电子转移活性自由基聚合的机理及适合该聚合体系的催化剂、配体、溶剂种类和单体适用范围，并探讨了单电子转移活性自由基聚合的发展前景。
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| 关 键 词： | 活性聚合 单电子转移活性自由基聚合 机理 外层电子转移 异裂 |
| 收稿时间： | 2010-05-10 |
| 修稿时间： | 2010-07-28 |
Current Situation and Perspectives of Single Electron Transfer Living Radical Polymerization |
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| DING Wei,SUN Ying,LV Chongfu,WEI Jijun,YU Tao. Current Situation and Perspectives of Single Electron Transfer Living Radical Polymerization[J]. Chinese Journal of Applied Chemistry, 2011, 28(3): 245-253. DOI: 10.3724/SP.J.1095.2011.00268 |
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| Authors: | DING Wei SUN Ying LV Chongfu WEI Jijun YU Tao |
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| Affiliation: | (Chemistry and Chemical Engineering College of Northeast Petroleum University,Daqing 163318) |
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| Abstract: | In this paper,we mainly discussed the involved mechanism in single electron transfer living radical polymerization.The types of catalysts,ligands,solvents as well as monomers suitable for such kinds of polymerizations have been also addressed in detail.In addition,the perspectives of this single electron transfer living radical polymerization was highlighted. |
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| Keywords: | living polymerization single electron transfer living radical polymerization mechanism outer-sphere electron transfer heterolysis |
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