| 三苯基锗不饱和烃基膦酸衍生物的合成和性质 |
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| 引用本文： | 尹汉东,马春林,张如芬,王勇.三苯基锗不饱和烃基膦酸衍生物的合成和性质[J].高等学校化学学报,2000,21(2):246. |
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| 作者姓名： | 尹汉东 马春林 张如芬 王勇 |
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| 作者单位： | 聊城师范学院化学系, 聊城 252059 |
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| 基金项目： | 教育部科学技术研究项目 |
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| 摘 要： | 随着倍半锗氧类化合物的合成及应用研究的日益广泛,含Ge_O键的烃基锗衍生物的合成及应用也逐渐引起了人们的关注.1984年,Lukevics等1]合成了具有抗癌活性的介吗川类化合物,1990年Kakimoto等2]报道了具有杀菌活性的环状烃基羧酸的合成与应用.
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| 关 键 词： | 三苯基锗 不饱和烃基膦酸 合成 生物活性 |
| 收稿时间： | 1999-05-05 |
Synthesis and Properties of Triphenylgermanium Derivatives of Unsaturated Alkylphosphonic Acid |
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| YIN Han-Dong,MA Chun-Lin,ZHANG Ru-Fen,WANG Yong.Synthesis and Properties of Triphenylgermanium Derivatives of Unsaturated Alkylphosphonic Acid[J].Chemical Research In Chinese Universities,2000,21(2):246. |
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| Authors: | YIN Han-Dong MA Chun-Lin ZHANG Ru-Fen WANG Yong |
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| Institution: | Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059, China |
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| Abstract: | Fourteen new triphenylgermanium derivatives of alkynyl or alkenyl phosphonic acid were synthesized by the reaction of corresponding triphenylgermanium chloride with alkynyl or alkenyl phosphates. All compounds were characterized by elemental analysis, IR, 1H NMRand MS. The results showed that bis(triphenylgermanium) alkynyl or alkenyl phosphonates are both four- and five-coordinated germanium and triphenylgermanium alkynyl or alkenyl phosphonates are five-coordinated germanium. |
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| Keywords: | Triphenylgermanium Unsaturated alkylphosphonic acid Synthesis Bioalogical activity |
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