Synthesis of 2-ethyl-2-methyl-2,3-dihydro-1H-indole, a new insecticide exhibiting juvenile hormone activity |
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| Authors: | E. A. Petrushkina V. N. Kalinin G. B. Ivanova V. A. Kheinman |
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| Affiliation: | (1) Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia;(2) All-Russia Research Institute of Chemical Means for Plant Protection, Moscow, Russia |
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| Abstract: | ![]()
Catalytic hydroamination of isoprene gave N-(1,2-dimethylprop-2-en-1-yl)aniline in a preparative yield. By heating at 260°C the product was converted into 2-ethyl-2-methyl-2,3-dihydro-1H-indole, a new ecologically safe insecticide exhibiting a juvenile hormone activity. Its insecticide properties against Tenebrio Molitor L. chrysalises were estimated at 7.5 points according to the Schmialek 9-point scale. |
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