多孔材料负载金催化剂的制备与应用*

本文综述了微孔材料和介孔材料负载型金催化剂的制备、表征与应用研究的最新进展，从多孔载体的选择（氧化物、微孔分子筛、介孔氧化物、介孔分子筛和介孔碳材料）、金的最新负载方法（沉积-沉淀法、溶胶-凝胶法、原位法/一步法和化学气相沉积法）与表征及其催化性能（一氧化碳低温氧化、氢气/氧气直接合成过氧化氢、直接合成环氧丙烷和有机物的选择性氧化）等方面详尽地评述了微孔材料和介孔材料负载型金催化剂研究概况。同时，提出了多孔材料负载金催化剂存在的一些问题，并展望了其研究和发展的方向。

Preparation and Application of Porous Material Supported Gold Catalysts

This review outlines recent development of preparation, characterization and application of microporous material and mesoporous material supported gold catalysts. The selection of the microporous supports or mesoporous supports (unmodified oxides, microporous molecular sieves, mesoporous oxides, mesoporous molecular sieves and mesoporous carbon materials), the latest preparation methods of porous material supported gold catalysts (deposition-precipitation, sol-gel method, in situ/one-step method and chemical vapor deposition) and characterizations, as well as catalytic performance (carbon monoxide low-temperature oxidation, direct synthesis of hydrogen peroxide from hydrogen and oxygen, direct propylene epoxidation in the presence of hydrogen and oxygen and selective oxidation of organic compounds) are summarized. Meanwhile, the problem, as well as the research and development direction of porous material supported gold catalysts is presented. Contents
1 Introduction
2 Preparation of porous material supported gold catalysts
2.1 Selection of support
2.2 Preparation methods
3 Catalytic performance and application of supported gold catalysts
3.1 CO low-temperature oxidation
3.2 Direct propylene epoxidation in the presence of H₂/O₂
3.3 Direct synthesis of H₂O₂ from H₂/O₂
3.4 Selective oxidation of organic compounds
4 Conclusion