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三七不同部位成分的谱学性质研究
引用本文:刘智,李赛君,田洪波,徐怡庄,吴瑾光. 三七不同部位成分的谱学性质研究[J]. 光谱学与光谱分析, 2005, 25(4): 579-583
作者姓名:刘智  李赛君  田洪波  徐怡庄  吴瑾光
作者单位:北京大学化学与分子工程学院,稀土材料及应用国家重点实验室,北京 100871
基金项目:国家重点基础研究发展规划项目 (G1 9980 61 30 7),国家自然科学基金 (50 2 0 30 0 1,2 0 1 71 0 0 4 ),科技部极端条件下物质的标准(2 0 0 2CCA0 1 90 0 ),北京大学中药现代研究中心基金 (2 0 1 0xc)资助项目
摘    要:采用不同溶剂提取了三七的不同部位,即提取三七皮和芯的化学成分,通过研究提取液的紫外-可见光谱(UV-Vis),傅里叶变换红外光谱(FTIR)、荧光光谱(FS)、电喷雾离子质谱(ESI-MS)及高效液相色谱(HPLC),寻找谱学特征与其化学成分的相关性,从化学成分的角度解释了三七皮与芯的药理效应差异的可能原因。

关 键 词:三七  谱学  色谱  
文章编号:1000-0593(2005)04-0579-05
收稿时间:2003-12-16
修稿时间:2003-12-16

Spectroscopic Studies on Different Chemical Composition between the Shell and Core of Radix Notoginseng
LIU Zhi,LI Sai-jun,TIAN Hong-bo,XU Yi-zhuang,WU Jin-guang. Spectroscopic Studies on Different Chemical Composition between the Shell and Core of Radix Notoginseng[J]. Spectroscopy and Spectral Analysis, 2005, 25(4): 579-583
Authors:LIU Zhi  LI Sai-jun  TIAN Hong-bo  XU Yi-zhuang  WU Jin-guang
Affiliation:The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
Abstract:Notoginseng(Sanqi) is one of the most important components of famous Chinese recipe(Yunan Baiyao) and possesses a wide variety of applications in clinical practice. It has been found that Sanqi of different size exhibits different curative effects. Such a phenomenon may be attributed to that the chemical constituent from shell region is different from that of core region. To prove the above-mentioned hypothesis, Ultraviolet-Visible(UV-Vis), FTIR, fluorescence spectroscopy, together with high performance liquid chromatography(HPLC) and electrospray ionization mass spectroscopy(ESI-MS) were utilized to study the variation of chemical compositions from shell and core regions of Sanqi. The results demonstrate that the chemical compositions of Sanqi from shell and core regions are different. In summary, differences in chemical composition between Sanqi shell and core were manifested from versatile aspects . Such differences shed a light on the different curative effects of Sanqi.
Keywords:Radix notoginseng  Spectroscopy  HPLC
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