13C RMN: Non-équivalences d'ammoniums quaternaires diastéréoisoméres |
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Authors: | A Solladi-Cavallo G Solladi |
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Institution: | A. Solladié-Cavallo,G. Solladié |
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Abstract: | 13C magnetic resonance spectra of six diastereomeric mixtures of quaternary ammonium salts were investigated. Assignment of the signals of the non-aromatic carbons and measurement of the non-equivalences allowed the determination of the ratio of isomers in the mixtures. A deshielding β effect and a shielding γ effect for the quaternisation were pointed out. |
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