Komplexchemie polyfunktioneller Liganden. XXXI. Komplexe des Tetrakis(diphenylphosphorylmethyl)-methan mit FeCl3, SnCl4 und SbCl5 |
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| Authors: | J Ellermann M Thierling |
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| Abstract: | Complex Chemistry of Polyfunctional Ligands. XXXI. Complexes of Tetrakis(diphenylphosphorylmethyl) methane with FeCl3, SnCl4, and SbCl5 CCH2P(O)(C6H5)2]4 forms with FeCl3 the compounds CCH2P(O)(C6H5)2]4 · 2FeCl3 and CCH2P(O)(C6H5)2]4 · 4 FeCl3. From their IR spectra ionic, spirocyclic structures have been derived. CCH2P(O)(C6H5)2]4 yields with SnCl4 and SbCl5 also spirocyclic compounds of the composition CCH2P(O)(C6H5)2]4 · 2 SnCl4 and CCH2P(O)(C6H5)2]4 · 4 SbCl5, but the SnCl4 derivative has a nonionic structure. |
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