| 2，4，6-三硝基间苯二酚钡一水化合物的热分解动力学(英) |
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| 引用本文： | 胡荣祖,陈三平,高胜利,宋纪蓉,史启祯,赵宏安,姚 朴,李 静.2，4，6-三硝基间苯二酚钡一水化合物的热分解动力学(英)[J].无机化学学报,2004,20(4):412-420. |
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| 作者姓名： | 胡荣祖 陈三平 高胜利 宋纪蓉 史启祯 赵宏安 姚 朴 李 静 |
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| 作者单位： | 1. 陕西省物理无机化学重点实验室/西北大学化学系,西安,710069
2. 陕西应用物理化学研究所,西安,710061 |
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| 基金项目： | 陕西省物理无机化学重点实验室科技基金资助项目(No.29鄄3，2001)，国防科工委火炸药燃烧重点实验室预研基金资助项目(No.514550101)。 |
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| 摘 要： | 0IntroductionBarium2,4,6鄄trinitroresorecinatemonohydrate,Ba(TNR)·H2O,hasgooddetonatingpropertiesandissensitivetoflame.Itcanbeusedasinitiatingagent,igniterpowderordelaypowder.Itspreparation1],pro鄄perties1],crystalstructure1]andthermalbehavior2]haveb…
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| 关 键 词： | Ba(TNR)·H2O DSC 非等温动力学 TG-DTA 热分解 |
Thermal Decomposition Kinetics of Barium 2,4,6-trinitroresorecinate Monohydrate |
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| HU Rong-Zu,CHEN San-Ping,GAO Sheng-Li,SONG Ji-Rong,SHI Qi-Zhen,ZHAO Hong-An,YAO Pu and LI Jing.Thermal Decomposition Kinetics of Barium 2,4,6-trinitroresorecinate Monohydrate[J].Chinese Journal of Inorganic Chemistry,2004,20(4):412-420. |
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| Authors: | HU Rong-Zu CHEN San-Ping GAO Sheng-Li SONG Ji-Rong SHI Qi-Zhen ZHAO Hong-An YAO Pu and LI Jing |
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| Abstract: | Studies of the non-isothermal decomposition of barium 2,4,6-trinitroresorecinate monohydrate, Ba(TNR)·H2O, were carried out by means of TG-DTA, DSC and IR. The thermal decomposition mechanism and associated kinetics were investigated. The kinetic parameters were obtained from an analysis of the DSC curves by integral and differential methods. The most probable kinetic model function of the dehydration reaction of Ba(TNR)·H2O was suggested by comparison of the kinetic parameters. |
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| Keywords: | Ba(TNR) H2O DSC non-isothermal kinetics TG-DTA thermal decomposition |
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