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Effects of nickel on the crystallization of Zr70Cu20Ni10 amorphous alloy
作者姓名:王焕荣  叶以富  张均艳  滕新营  闵光辉  石志强  田学雷
作者单位:Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China;Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China; College of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China;Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China;Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China;Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China;Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China
基金项目:Project supported by the National Natural Science Foundation of China (Grant No 59871025).
摘    要:

关 键 词:crystallization    Zr-Cu-based  amorphous  alloys    x-ray  diffraction    differential  scanning  calorimetry
收稿时间:2001-12-06

Effects of nickel on the crystallization of Zr70Cu20Ni10 amorphous alloy
Wang Huan-Rong,Ye Yi-Fu,Zhang Jun-Yan,Teng Xin-Ying,Min Guang-Hui,Shi Zhi-Qiang and Tian Xue-Lei.Effects of nickel on the crystallization of Zr70Cu20Ni10 amorphous alloy[J].Chinese Physics B,2002,11(6):592-595.
Authors:Wang Huan-Rong  Ye Yi-Fu  Zhang Jun-Yan  Teng Xin-Ying  Min Guang-Hui  Shi Zhi-Qiang and Tian Xue-Lei
Institution:Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China; Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China; College of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China
Abstract:Differential scanning calorimetry (DSC) and x-ray diffraction (XRD) are employed to investigate the effects of nickel on the crystallization of the amorphous Zr70Cu20Ni10 alloy. We have found that the crystallization process of the amorphous Zr70Cu20Ni10 alloy is strongly influenced by the addition of nickel. Addition of 10 at% Ni to the Zr70Cu30 amorphous alloy makes the crystallization process proceed from a single-stage mode to a double-stage mode. The activation energy for crystallization of the amorphous Zr70Cu20Ni10 alloy is calculated to be about 388kJ·mol-1 on the basis of the Kissinger equation. The effects of nickel on the crystallization of the amorphous Zr70Cu20Ni10 alloy are discussed in terms of the genetics of metals.
Keywords:crystallization  Zr-Cu-based amorphous alloys  x-ray diffraction  differential scanning calorimetry
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