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Rhodium-catalyzed intramolecular C-H insertion of alpha-aryl-alpha-diazo ketones |
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| Authors: | Taber Douglass F Tian Weiwei |
| Affiliation: | Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. taberdf@udel.edu |
| Abstract: | Direct diazo transfer proceeds smoothly with alpha-aryl ketones. The derived alpha-aryl-alpha-diazo ketones cyclize efficiently with Rh catalysis to give the corresponding alpha-aryl cyclopentanones. |
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