Palladium(ii) driven self-assembly of a saturated quadruple-stranded metallo helicate |
| |
Authors: | Debakanta Tripathy Amlan K Pal Garry S Hanan Dillip Kumar Chand |
| |
Institution: | Department of Chemistry, IIT Madras, Chennai, India. dillip@iitm.ac.in. |
| |
Abstract: | Complexation of the bridging bidentate ligand N,N'-(pyridine-2,6-diyl)dinicotinamide, L with palladium(ii) resulted in a single discrete M(2)L(4) self-assembly, 1, in a quantitative manner. The entropically-controlled assembly of 1 resulted in a rare saturated, quadruple-stranded metallo-helicate, in which both the left-handed (M) and right-handed (P) helicates exist in the crystal structure. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|