Infrared spectra and rotational isomerism of certain crystalline vinyl ethers |
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Authors: | B. A. Trofimov A. S. Atavin A. V. Gusarov |
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Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions In contrast to conformationally inhomogeneous liquid vinyl ethers, crystalline trialkylvinyloxyalkylammonium salts, according to the data of IR spectroscopy, exist practically only in the form of a flat (conjugated) conformation. An exception is trimethylvinyloxyethylammonium bromide, which crystallizes almost exclusively in a nonplanar form.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1457–1460, July, 1971. |
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